You are trying to convert nrrd files into a RT Structure Set using 3D Slicer? By coincidence, I documented this procedure earlier today.
- Load all images. At time of load, click “Labelmap” checkbox for each structure
 - Go to Segmentation module
 - For “Active segmentation”, choose “Create new segmentation”
 - For each structure, repeat:
4a) In “Export/Import segments”, choose structure, and import as labelmap - Click on one of the segments, and then click “Edit selected”
 - Set the “Master volume” to your CT
 - Go to Data module.
 - On background, right click choose “Create new subject”
 - On subject, right click choose “Create child study”
 - Drag the CT and segmentation node onto the child study
 - Right click on study, choose “Export to DICOM”
 - Enjoy your newly created DICOM-RT file